When there is no number after an element, as is the case with Calcium (Ca), we assume there to be one atom of that element. For example, in Ca3(PO4)2 we have only one Ca atom.
For Ca3(PO4)2 there are a total of 13 atoms in the compound.
To find the number of atoms in one mole of Ca3(PO4)2 we multiply the number of each atom (for example there are two P atoms) by Avogadro's number, 6.02 x 10^23.
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